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The interaction of carbon monoxide (CO) with vapour-deposited water(H2O) ices has been studied using temperature programmed desorption (TPD) and Fourier transform reflection-absorption infrared spectroscopy (FT-RAIRS) over a range of astrophysically relevant temperatures. Such measurements have shown that CO desorption from amorphous H2Oices is a much more complex process than current astrochemical models suggest. Re-visiting previously reported laboratory experiments (Collings et al., 2003), a rate model has been constructed to explain, in a phenomenological manner, the desorption of CO over astronomically relevant time scales. The model presented here can be widely applied to a range of astronomical environments where depletion of CO from the gas phase is relevant. The model accounts for the two competing processes of CO desorption and migration, and also enables the entrapment of some of the CO in the ice matrix and its subsequent release as the water ice crystallises and then desorbs. The astronomical implications of this model are discussed. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
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本文使用红外天文卫星(IRAS)巡天数据的最新版本IRAS天空巡天图(ISSA),经过进一步处理,得到了S140S141和S142SharplessHII区-分子云复合体的红外发射强度、温度及其光深的分布.在此基础上对各HII区的一些物理参量进行了统计分析,得到了分子云复合体的红外发射总光度以及复合体中尘埃的分布情况,对小尺度尘埃(VSG)的丰度进行了分析.并对各恒星形成区中的致密团块进行了研究,揭示出其中一些可能的恒星形成区域.同时,对S140区中的有关红外点源作出了能谱分析,并对S141区的激发星进行了讨论.  相似文献   
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A model is proposed for the formation of water ice mantles on grains in interstellar clouds. This occurs by direct accretion of monomers from the gas, be they formed by gas or surface reactions. The formation of the first monolayer requires a minimum extinction of interstellar radiation, sufficient to lower the grain temperature to the point where thermal evaporation of monomers is just offset by monomer accretion from the gas. This threshold is mainly determined by the adsorption energy of water molecules on the grain material; for hydrocarbon material, chemical simulation places this energy between 0.5 and 2 kcal mol−1, which sets the (true) visible extinction threshold at a few magnitudes. However, realistic distributions of matter in a cloud will usually add to this an unrelated amount of cloud core extinction, which can explain the large dispersion of observed (apparent) thresholds. Once the threshold is crossed, all available water molecules in the gas are quickly adsorbed, because the grain cools down and the adsorption energy on ice is higher than on bare grain. The relative thickness of the mantle, and, hence, the slope of  τ3( A v)  depend only on the available water vapour, which is a small fraction of the oxygen abundance. Chemical simulation was also used to determine the adsorption sites and energies of O and OH on hydrocarbons and study the dynamics of formation of water molecules by surface reactions with gaseous H atoms, as well as their chances to stick in situ.  相似文献   
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This paper reports results from an experiment designed to measure the nascent rovibrational population of H2 molecules that have formed through the heterogeneous recombination of H atoms on the surface of cosmic dust analogues under conditions approaching those of the interstellar medium (ISM). H2 that has formed on a highly oriented pyrolytic graphite (HOPG) surface has been detected, using laser induced resonance-enhanced multi-photon ionization (REMPI), in the v = 1 (J= 0–3) rovibrational states at surface temperatures of 30 K and 50 K. These excited product molecules display rotational temperatures significantly higher than the target surface temperature. These first results suggest that a considerable proportion of the binding energy released on formation of the H2 is deposited in the surface, in addition to internal excitation of the product molecules. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
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Genetic diversity and differentiation of the oyster Crassostreaplicatula populations from China's coast were studied basedon seven microsatellite loci.All loci showed high polymorphism for all five C.plicatula populations,with an average number of alleleper locus of 19.3-27.9 and an average expected heterozygosity of 0.889-0.952.Significant departures from Hardy-Weinberg equilib-rium and deficits of heterozygotes were observed over most populations at each locus,which were fully explained by null alleles.Microsatellite analysis revealed significant subdivision in the C.plicatula populations.According to the neighbor-joining tree con-structed on the basis of the D,A distance,the five populations fell into three regional groups,showing a relatively homogeneous geneticstructure in geographically close populations.Assignation tests correctly assigned high percentages of individuals to their originalpopulations and groups,and also confirmed the existence of genetic differentiation among C.plicatula populations.The results ob-tained in this study will facilitate the formulation of appropriate fisheries management programs,stock identification and conservationof biodiversity for the species.  相似文献   
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Possible detection of signatures of structure formation at the end of the 'dark age' epoch  ( z ∼ 40–20)  is examined. We discuss the spectral–spatial fluctuations in the cosmic microwave background radiation (CMBR) temperature produced by elastic resonant scattering of CMBR photons on deuterated hydrogen (HD) molecules located in protostructures moving with peculiar velocity. Detailed chemical kinematic evolution of HD molecules in the expanding homogeneous medium is calculated. Then, the HD abundances are linked to protostructures at their maximum expansion, whose properties are estimated by using the top-hat spherical approach and the Λ cold dark matter (ΛCDM) cosmology. We find that the optical depths in the HD three lowest pure rotational lines for high-peak protohaloes at their maximum expansion are much higher than those in LiH molecule. The corresponding spectral–spatial fluctuation amplitudes, however, are probably too weak to be detected by current and forthcoming millimetre telescope facilities. We extend our estimates of spectral–spatial fluctuations to gas clouds inside collapsed CDM haloes by using results from a crude model of HD production in these clouds. The fluctuations for the highest peak CDM haloes at redshifts ∼20–30 could be detected in the future. Observations will be important to test model predictions of early structure formation in the Universe.  相似文献   
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